July 7, 2004 -- Cambodian Prime Minister Hun Sen offers Jolie citizenship in thanks for her tireless charity work. On Jolie's trip there, she pledges $1.5 million to an environmental project.
March 9, 2005 -- At Washington, D.C.'s National Press Club, Jolie outlines plans for the National Center for Refugee and Immigrant Children, an organization she helped launch, which is to provide legal assistance for thousands of immigrant children in the United States. She tells reporters she plans to adopt another child so that Maddox can have an "African brother."
April 2005 -- Fueling rumors that they are now a couple, Jolie and Brad Pitt are photographed holding hands on the beach of Mombassa, Kenya, with Jolie's son, Maddox. They visit an AIDS treatment center in Ethiopia.
Sept. 5, 2005 -- "Shocked" at the response to Hurricane Katrina, Jolie writes to the White House and members of Congress, saying in a statement that New Orleans is "very close to my heart."
Sept. 16, 2005 -- In a deal reportedly valued at $12 million, Jolie becomes the new face of the St. John fashion line. In addition to working for the California clothing manufacturer, she'll head the company's charitable foundation.
Oct. 27, 2005 -- Declaring that charitable work is "the greatest thing in my life," Jolie accepts the U.N. Global Humanitarian Action Award.
Nov. 28, 2005 -- After Pitt and Jolie spend Thanksgiving in Pakistan visiting earthquake victims, Pitt pledges to buy 40 orthopedic beds for an Islamabad hospital at a cost of $100,000.
Jan. 30, 2006 -- Jolie addresses the World Economic Forum in Davos, Switzerland, and warns those present not to be starstruck by her presence, and to focus on humanitarian efforts in war-torn areas. "I just think if I can ask anything, it's for everybody in this room, including myself, to stay focused on the issues."