The couple, who met on the set of "The Fresh Prince of Bel-Air" in 1995, have had a lot of different roles over the years, most recently founding the New Village Leadership Academy (NVLA), a private elementary school in Calabasas, Calif., which opened its doors this week for the start of the 2009-10 school year.
Coupled with the long-time "secretly Scientologist" rumors that have surrounded the Smiths, the school's opening has attracted curiosity.
"I've talked to Tom about it. [There's] lots of incredible, wonderful concepts [but my wife] Jada and I don't necessarily believe in organized religion. I was raised in a Baptist household, and my grandmother would get up out of her casket [if I became a Scientologist]," Smith told the World Entertainment News Network, a news wire, in 2006.
Also creating questions are reports that tax returns for 2008 from the Smith's charitable foundation show that the couple gave a combined $122,500 in donations to groups affiliated with the Church of Scientology. The Smiths reportedly donated a total of $1.3 million to a variety of religious, civic and arts groups that year. Smith's biggest single contribution was to Yesha Ministries of Philadelphia. He gave the Christian-based organization run by the Rev. James Robinson $250,000. Another $200,000 went to a Christian ministry in Los Angeles called "Living Waters." The foundation also donated to a Los Angeles mosque, as well as the Yitzhak Rabin Memorial Center and other religious groups. When asked about the donations, Will Smith's publicist, Pat Kinsley, told ABC News.com that her client doesn't comment on his philanthropic work.
In an interview with Ebony magazine earlier this year, Pinkett-Smith said that the NVLA was not tied to Scientology: "All I can say is it is not a Scientology school," she told the magazine. "Now, If you don't trust me, and you are questioning my integrity, that's a whole different matter. That is straight evil to think that I would bring families into that educational institution and then try to get them to convert into some religion."
Despite such statements, skeptics continue to raise questions about whether the Smiths have ties to Scientology, especially when it comes to the NVLA.
It operates under the assumption that there are three "barriers" to learning that children must identify and overcome.
Critics claim Study Technology is repackaged Scientology. One professor who has closely followed Scientology suggested the "three barriers" technique is used as a means of familiarizing children with some of the vocabulary often used in Scientology teachings, and several educators told ABCNews.com that the "three barriers" philosophy is a fundamentally flawed teaching tool.