Jason Sudeikis and Alison Brie On Leaving Hit Shows

From “Saturday Night Live” and “Mad Men” to “Community” and “Horrible Bosses."

“It was a big year of farewells for me," Brie told ABC News. "I think I had a public tear on set with everybody saying goodbye."

And for Sudeikis, it was much the same, speaking on his two-time departure from SNL.

With those shows now behind them, could it be that Sudeikis and Brie were meant to be together ... on film? For the first time, they've teamed up on screen in the new romantic comedy "Sleeping with Other People.” Both on screen and off, they seem like old friends just hanging out having a good time.

Brie said her old boss, Dan Harmon, who is the writer and producer of “Community” actually once tried to set them up as a couple.

"Years before this project came out, he had actually texted me and wanted to set me up with Jason. And I said yeah."

"And two months later I met the love of my life," Brie said, speaking of fiancé Dave Franco. "And five years later we met each other and made this movie".The big question in their new film is can two people with great chemistry truly just be friends.

“The trick is to be madly in love with someone else," said Brie. “But both people have to be in love with someone else.”

"Sleeping with Other People" is in theaters now.