Russian forces are advancing on Mykolaiv, another key city in southern Ukraine, the regional governor warned Friday.

In a video message posted on social media, Mykolaiv Oblast Gov. Vitaliy Kim said Russian troops are moving on Mykolaiv city from two directions and that some have already entered the city limits but are not yet inside in significant numbers.

The city is preparing to defend itself, according to Kim.

"Don't panic," Kim said. "At the moment, the enemy is approaching from two directions but they're not on our streets yet. We're preparing the defenses, so women and children should get home now and the men join the defense lines."

Kim said the Ukrainian military has a large amount of armour in Mykolaiv and urged residents "not to shoot at every vehicle," since some could be Ukrainian.

"No need to shoot at everything that's moving in the city. There's a lot of our armor in the city," he said. "{lease do not shoot inside the city, there's no enemy here yet, but they are approaching."

-ABC News' Patrick Reevell

The U.S. Embassy in Kyiv took to Twitter on Friday to condemn Russia's shelling of Ukraine's Zaporizhzhia nuclear power plant, the largest in Europe.

"It is a war crime to attack a nuclear power plant," the embassy tweeted. "Putin's shelling of Europe's largest nuclear plant takes his reign of terror one step further."

NATO Secretary-General Jens Stoltenberg met with U.S. Secretary of State Antony Blinken and other NATO foreign ministers in Brussels on Friday morning to discuss the response to the ongoing Russian invasion of Ukraine.

During a press conference prior to the meeting at NATO headquarters, Blinken and Stoltenberg condemned Russia's attacks on civilians in Ukraine and expressed concern over the reports of Russian shelling at Ukraine's largest nuclear power plant.

"This just demonstrates the recklessness of this war and the importance of ending it, and the importance of Russia withdrawing all its troops and engage in good faith in diplomatic efforts," Stoltenberg told reporters. "We provide support to Ukraine. At the same time, NATO is not part of the conflict. NATO is a defensive alliance, we don't seek war conflict with Russia."

Blinken emphasized that NATO and the United States "seek no conflict."

"But if conflict comes to us, we're ready for it," he added. "And we will defend every inch of NATO territory."

The head of the United Nations nuclear watchdog said Friday that no radioactive material was released at Ukraine's largest nuclear power plant amid shelling from Russian forces overnight.

The shelling sparked a fire in a training building at the Zaporizhzhia nuclear power plant, the largest in Europe, in the eastern Ukrainian city of Enerhodar. The blaze has since been extinguished, according to Ukraine's State Emergency Service.

Two security employees at the plant were injured during the incident, according to International Atomic Energy Agency (IAEA) Director-General Rafael Mariano Grossi.

"The safety systems at the six reactors were not effected," Grossi said at a press conference in Vienna on Friday morning. "No radioactive material was released."

"We are following the situation very, very closely," he added.

-ABC News' Joe Simonetti

The U.S. Department of Commerce announced Friday that it will restrict the export of U.S. luxury goods to Russia and Belarus, as well as "certain Russian and Belarusian oligarchs and malign actors located worldwide," as a result of their actions in Ukraine.

The Department of Commerce said it will impose restrictions on the export, reexport and transfer of luxury items including certain spirits, tobacco products, clothing items, jewelry, vehicles and antique goods.

"Putin’s war of choice in Ukraine continues to take a devastating toll on innocent civilians in Ukraine, fueling one of the worst humanitarian crises Europe has seen in decades," Secretary of Commerce Gina Raimondo said in a statement.

Raimondo added, "Putin and the oligarchs who fund him have gotten rich off of Putin’s rampant corruption and the exploitation of the Russian people. We will not allow Putin and his cronies to continue living in opulence while causing tremendous suffering throughout Eastern Europe. Today’s action takes away another source of comfort and reminds them that Russia is increasingly isolated."

-ABC News' Luke Barr