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George Stephanopoulos goes one-on-one with U.S. Ambassador to the U.N. Samantha Power and Massachusetts Gov. Deval Patrick.

Plus, we speak with 2016 GOP frontrunner Sen. Rand Paul, R-Ky., Sunday on "This Week."

And the powerhouse roundtable debates all the week's politics, including the resignation of HHS Secretary Kathleen Sebelius, with ABC News political analyst Matthew Dowd, Republican strategist and ABC News contributor Ana Navarro, Democratic strategist James Carville, syndicated radio host Laura Ingraham, and University of California, Berkeley professor and former Clinton Labor secretary Robert Reich.

See the whole political picture, Sunday on "This Week."

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Sunday on #ThisWeek: talking Jeb's "act of love", Cheney & containing Iran w/ Rand Paul in NH. Check out the studio pic.twitter.com/sRHXnAAWFc

- Jonathan Karl (@jonkarl) April 11, 2014